結論

N-酰(xian)基氨(an)(an)基酸(suan)表(biao)(biao)面(mian)活(huo)性劑是一類"綠(lv)色"表(biao)(biao)面(mian)活(huo)性劑，可替代傳統表(biao)(biao)面(mian)活(huo)性劑。本(ben)文利用植物(wu)(wu)油(you)(you)和(he)(he)(he)相(xiang)應的(de)(de)(de)氨(an)(an)基酸(suan)直接合成(cheng)了六(liu)種N-酰(xian)基氨(an)(an)基酸(suan)表(biao)(biao)面(mian)活(huo)性劑。它們的(de)(de)(de)結構(gou)通過IR和(he)(he)(he)MS確認。獲得了表(biao)(biao)面(mian)活(huo)性劑的(de)(de)(de)表(biao)(biao)征參數，包括(kuo)CMC、γCMC、Γmax、Amin、ΔGads和(he)(he)(he)ΔGmic。有趣的(de)(de)(de)是，聚集行為很大程(cheng)度上取(qu)決于氨(an)(an)基酸(suan)殘基和(he)(he)(he)疏水鏈的(de)(de)(de)結構(gou)。蓖麻油(you)(you)衍生物(wu)(wu)尾部羥(qian)基的(de)(de)(de)存在傾向于自組裝成(cheng)球(qiu)狀囊泡，而(er)頭部帶有羥(qian)基的(de)(de)(de)酰(xian)基絲氨(an)(an)酸(suan)衍生物(wu)(wu)形成(cheng)管狀囊泡。

致謝

作者感謝國家重點研發計(ji)劃（2017YFB0308701）、國家自然科(ke)學(xue)基金(jin)（21676003）、北(bei)京市科(ke)技項(xiang)目（D17110500190000）和(he)北(bei)京工(gong)商大學(xue)青(qing)年基金(jin)對本工(gong)作的支(zhi)持(chi)學(xue)者基金(jin)（PXM2018_014213_000033）。

附錄A.補(bu)充資(zi)料與本文(wen)相關的補(bu)充資(zi)料可在網絡版(ban)doi中(zhong)找到(dao)：//doi.org/10.1016/j.colsurfa.2018.09.042。

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植物油中N-酰基氨基酸表面活性劑的界面活性和聚集行為——摘要、簡介

植物油中N-酰基氨基酸表面活性劑的界面活性和聚集行為——材料和方法

植物油中N-酰基氨基酸表面活性劑的界面活性和聚集行為——結果和討論

植物油中N-酰基氨基酸表面活性劑的界面活性和聚集行為——結論、致謝！